Uncertainty of relative sensitivity factors in Glow Discharge Mass Spectrometry

From National Research Council Canada

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DOIResolve DOI: http://doi.org/10.1088/1681-7575/aa83d6
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  1. National Research Council Canada. Measurement Science and Standards
TypeArticle
Journal titleMetrologia
ISSN0026-1394
1681-7575
Subjectglow discharge mass spectrometry; calibration model; analyte/matrix interchangeability; relatives sensitivity factors; least squares adjustment
Abstract
The concept of relative sensitivity factors required for the correction of the measured ion beam ratios in pin-cell Glow Discharge Mass Spectrometry (GD-MS) is examined in detail. We propose a data-driven model for predicting relative response factors which relies on nonlinear least squares adjustment and analyte/matrix interchangeability phenomena. The model provides a self-consistent set of response factors for any analyte/matrix combination of any element that appears as either analyte or matrix in at least one known response factor.
Publication date
PublisherIOP Publishing
LanguageEnglish
Peer reviewedYes
NPARC number23002149
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Record identifier2cbae90a-128b-457a-b054-20bf7422c8f6
Record created2017-08-25
Record modified2017-08-25
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