| DOI | Trouver le DOI : https://doi.org/10.1149/2.0051501eel |
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| Auteur | Rechercher : Novitski, David; Rechercher : Xie, Zhong1; Rechercher : Holdcroft, Steven |
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| Affiliation du nom | - Conseil national de recherches du Canada. Énergie, les mines et l'environnement
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| Format | Texte, Article |
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| Sujet | Diffusion; Electrodes; Electrolytic reduction; Ionomers; Lanthanum compounds; Microelectrodes; Oxygen; Platinum; Reduction; Electrochemical Generation; Open circuit potential; Oxygen diffusion coefficients; Oxygen reduction reaction; Perfluorosulfonic acid; Perfluorosulfonic acid ionomers; Potential step measurements; Solid-state electrochemical cells; Interface states |
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| Résumé | Chronoamperometric analysis of the oxygen reduction reaction (ORR) at Pt microelectrode | perfluorosulfonic acid (PFSA) ionomer interfaces in a solid state electrochemical cell reveals an increase in both the oxygen diffusion coefficient (Db) and oxygen permeability (Dbcb) upon consecutive potential step measurements. From a vapor-equilibrated, electrochemically unperturbed state under conditions of 70% RH and 50°C, Db and Dbcb increased by factors of 2 and 1.5, respectively. Db and Dbcb return to their initial values after resting the electrode at the open circuit potential. The electrochemical generation of water is believed responsible for the time-dependent mass transport parameters of ORR. |
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| Date de publication | 2014-11-01 |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 21275753 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | a858165c-c3c7-4d3b-8e53-6360d6ece4f4 |
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| Enregistrement créé | 2015-07-14 |
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| Enregistrement modifié | 2020-04-22 |
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