| DOI | Trouver le DOI : https://doi.org/10.1016/j.cplett.2004.05.098 |
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| Auteur | Rechercher : Zgierski, Marek1; Rechercher : Lim, Edward |
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| Affiliation | - Conseil national de recherches Canada. Institut Steacie des sciences moléculaires du CNRC
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| Format | Texte, Article |
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| Résumé | Evidence is presented for direct involvement of [pi][sigma]C[6-point triple bond; length half of m-dash]C* state in the intramolecular charge transfer of p-disubstituted diphenylacetylene containing an electron-donating group at one end and an electron-withdrawing group at the other. Comparison of the computed potential energy curves and the experimental transient absorption spectra with the corresponding data for N,N-dimethylaminobenzonitrile (DMABN) suggests that the [pi][sigma]C[6-point triple bond; length half of m-dash]N* state may also play a central role in the photoinduced electron-transfer of DMABN and related molecules. |
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| Date de publication | 2004-07-21 |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 12328099 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 88c2ce46-6a1c-4e35-b138-0a24d1c3da0a |
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| Enregistrement créé | 2009-09-10 |
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| Enregistrement modifié | 2023-06-23 |
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