A density functional tight binding model with an extended basis set and three-body repulsion for hydrogen under extreme thermodynamic conditions

Par Conseil national de recherches du Canada

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DOI	Trouver le DOI : https://doi.org/10.1021/jp5036713
Auteur	Rechercher : Srinivasan, Sriram Goverapet; Rechercher : Goldman, Nir; Rechercher : Tamblyn, Isaac; Rechercher : Hamel, Sebastien; Rechercher : Gaus, Michael
Format	Texte, Article
Résumé	We present a new DFTB-p3b density functional tight binding model for hydrogen at extremely high pressures and temperatures, which includes a polarizable basis set (p) and a three-body environmentally dependent repulsive potential (3b). We find that use of an extended basis set is necessary under dissociated liquid conditions to account for the substantial p-orbital character of the electronic states around the Fermi energy. The repulsive energy is determined through comparison to cold curve pressures computed from density functional theory (DFT) for the hexagonal close-packed solid, as well as pressures from thermally equilibrated DFT-MD simulations of the liquid phase. In particular, we observe improved agreement in our DFTB-p3b model with previous theoretical and experimental results for the shock Hugoniot of hydrogen up to 100 GPa and 25000 K, compared to a standard DFTB model using pairwise interactions and an s-orbital basis set, only. The DFTB-p3b approach discussed here provides a general method to extend the DFTB method for a wide variety of materials over a significantly larger range of thermodynamic conditions than previously possible.
Date de publication	2014-06-24
Maison d’édition	American Chemical Society
Dans	The Journal of Physical Chemistry A 118, nº 29 : 5520–5528.
Langue	anglais
Publications évaluées par des pairs	Oui
Publication du CNRC	Cette publication n’est pas du CNRC Ce sont des publications qui ont été rédigées par un auteur du CNRC, mais avant que celui-ci soit employé du CNRC.
Numéro NPARC	23003155
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Identificateur de l’enregistrement	79bde094-a298-48bc-a252-082fbfb0e850
Enregistrement créé	2018-05-02
Enregistrement modifié	2020-05-30

Date de modification :: 2024-10-09