Free radicals by mass spectrometry. V. The ionization potentials of methyl, allyl, and benzyl radicals

DOI	Trouver le DOI : https://doi.org/10.1063/1.1740136
Auteur	Rechercher : Lossing, F.P.¹; Rechercher : Ingold, K. U.¹; Rechercher : Henderson, I.H.S.¹
Affiliation	Conseil national de recherches Canada
Format	Texte, Article
Résumé	The ionization potentials of methyl, allyl, and benzyl radicals have been measured directly by electron impact. The values found were methyl 9.95±0.03 ev, allyl 8,16±0.03 ev, and benzyl 7.73±0.08 ev. The radicals were produced by thermal decomposition of suitable compounds in a mass spectrometer designed for the study of free radicals. Reactions of the radicals after formation led to the expected dimers, but the disproportionation reactions were found to be negligibly slow.
Date de publication	1954
Dans	The Journal of Chemical Physics 22, nº 4 : 621–625.
Langue	anglais
Publications évaluées par des pairs	Oui
Numéro NPARC	21276766
Exporter la notice	Exporter en format RIS
Signaler une correction	Signaler une correction (s'ouvre dans un nouvel onglet)
Identificateur de l’enregistrement	6fa9badf-7406-4585-b814-1ac940d69741
Enregistrement créé	2015-10-13
Enregistrement modifié	2020-03-12

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