Resonance Raman spectra of chymotrypsin acyl enzymes

DOI	Trouver le DOI : https://doi.org/10.1016/0006-291X(74)90621-4
Auteur	Rechercher : Carey, P.; Rechercher : Schneider, H.
Format	Texte, Article
Résumé	Resonance Raman spectra of cinnamoyl and α-toluyl acyl enzymes of α-chymotrypsin have been obtained. Bands associated with the aromatic portion of the acylating groups were identified and could be distinguished in a cinnamoyl derivative from those associated with the ethylenic residue. Spectral differences in the acyl enzyme relative to substrate and product were observed. These differences, which represent changes in vibrational modes of substrate bonds due to specific interaction with the active site, provide a novel approach to the study of the catalytic mechanisms of enzymes.
Date de publication	1974-04-08
Maison d’édition	Elsevier
Dans	Biochemical and Biophysical Research Communications 57, nº 3 : 831–837.
Langue	anglais
Publications évaluées par des pairs	Oui
Numéro du CNRC	CAREY1974A
Numéro NPARC	9375345
Exporter la notice	Exporter en format RIS
Signaler une correction	Signaler une correction (s'ouvre dans un nouvel onglet)
Identificateur de l’enregistrement	47a2e4b4-6ce8-473d-b286-71a5ba806629
Enregistrement créé	2009-07-10
Enregistrement modifié	2020-03-13

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