| DOI | Trouver le DOI : https://doi.org/10.1007/s10854-018-0409-y |
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| Auteur | Rechercher : Alam, Kazi M.; Rechercher : Kar, Piyush; Rechercher : Thakur, Ujwal K.; Rechercher : Kisslinger, Ryan; Rechercher : Mahdi, Najia; Rechercher : Mohammadpour, Arash; Rechercher : Baheti, Payal A.; Rechercher : Kumar, Pawan; Rechercher : Shankar, Karthik1 |
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| Affiliation | - Conseil national de recherches Canada. Nanotechnologie
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| Format | Texte, Article |
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| Résumé | Aqueous suspensions of cellulose nanocrystals were blended with Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) [PEDOT:PSS], and cast into thin films. The morphology, structure and electrical properties of the resulting nanocomposite thin films were thoroughly characterized. We found that the CNC–PEDOT:PSS blends self-organize into a layered vertical stack with a pitch of 100–200 nm while retaining a continuous percolation network for PEDOT. Atomic force microscopy, dynamic light scattering and multi-angle light scattering measurements confirmed the wrapping of polymer chains around the rod-like CNCs. The blended films exhibited improved molecular ordering of the PEDOT chains with concomitant improvement in the carrier mobility. The remarkable self-organization and enhanced structural order enabled the CNC–PEDOT:PSS blends to exhibit a high conductivity typical of PEDOT:PSS even when the content of the insulating CNCs in the nanocomposite was as high as 50 wt%. |
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| Date de publication | 2018-12-19 |
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| Maison d’édition | Springer |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 376dd7f6-a2e7-4649-b332-a08affb50d9b |
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| Enregistrement créé | 2021-08-12 |
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| Enregistrement modifié | 2021-08-12 |
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