| DOI | Trouver le DOI : https://doi.org/10.1016/S0040-4020(97)00332-3 |
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| Auteur | Rechercher : Bartberger, M.D.; Rechercher : Dolbier Jr., W.R.; Rechercher : Lusztyk, J.1; Rechercher : Ingold, K. U.1 |
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| Affiliation | - Conseil national de recherches du Canada
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| Format | Texte, Article |
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| Sujet | fluorinated hydrocarbon; organofluorine derivative; calculation; drug synthesis; electricity; in vitro study; pressure; quantum chemistry; reaction analysis; temperature; theoretical study; thermodynamics |
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| Résumé | Absolute rate constants for hydrogen abstraction from n-Bu3SnH by a number of partially-fluorinated and fully fluorinated n-alkyl radicals have been measured. The C-H and C-C bond dissociation energies for a number of pertinent hydrofluorocarbons have been calculated by DFT. The rate data are compared with those for addition of the same radicals to styrene, and the reactivities of these radicals are discussed in terms of their electronegativies, their structure and the thermodynamics of their reactions. |
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| Date de publication | 1997 |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 21276503 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 1ab725d1-e85c-441b-b257-5b7ba977a2ed |
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| Enregistrement créé | 2015-10-13 |
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| Enregistrement modifié | 2020-03-20 |
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