| DOI | Resolve DOI: https://doi.org/10.1039/B511710K |
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| Author | Search for: Fielicke, Andre; Search for: Helden, Gert von; Search for: Meijer, Gerard; Search for: Simard, Benoit1; Search for: Rayner, David1 |
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| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Abstract | Vibrational spectra of NO ligands adsorbed on cationic gold clusters are obtained using IR multiphoton dissociation spectroscopy. We observe a strong oscillation of the NO stretching frequency with increasing cluster size that reveals a clear odd-even dependence in the strength of the NO bond. For the corresponding CO complexes, no oscillation is found. This behaviour can be understood on the basis of the character and occupation of the frontier orbitals of the complexes. |
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| Publication date | 2005 |
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| In | |
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| Peer reviewed | Yes |
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| NPARC number | 12329008 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | eddc547f-9ee8-47fc-a895-579cd4d855cf |
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| Record created | 2009-09-10 |
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| Record modified | 2020-04-07 |
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