Absolute rate constants for the decarbonylation of the phenylacetyl radical

DOI	Resolve DOI: https://doi.org/10.1021/j100227a001
Author	Search for: Lunazzi, L.¹; Search for: Ingold, K. U.¹; Search for: Scalano, J.C.¹
Name affiliation	National Research Council of Canada
Format	Text, Article
Abstract	The rate of α scission of the phenylacetyl radical has been determined by laser flash photolysis in isooctane, methanol, and tetrahydrofuran. There is no significant solvent effect on the rate. In isooctane, the rate constant for decarbonylation can be represented by log (k/s-1) = (12.0 ± 0.3) - (6.9 ± 0.4)/2.3RT kcal/mol. © Copyright, 1983, by the American Chemical Society.
Publication date	1983
In	The Journal of Physical Chemistry 87, no. 4 (1983): 529–530.
Language	English
Peer reviewed	Yes
NPARC number	21276462
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Record identifier	e89bf005-3fe4-4f98-b9c6-0dc4c6be91de
Record created	2015-10-13
Record modified	2020-03-13