Absolute rate constants for the decarbonylation of the phenylacetyl radical

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/j100227a001
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  1. National Research Council Canada
FormatText
TypeArticle
Journal titleThe Journal of Physical Chemistry
ISSN0022-3654
Volume87
Issue4
Pages529–530
Abstract
The rate of α scission of the phenylacetyl radical has been determined by laser flash photolysis in isooctane, methanol, and tetrahydrofuran. There is no significant solvent effect on the rate. In isooctane, the rate constant for decarbonylation can be represented by log (k/s-1) = (12.0 ± 0.3) - (6.9 ± 0.4)/2.3RT kcal/mol. © Copyright, 1983, by the American Chemical Society.
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LanguageEnglish
Peer reviewedYes
NPARC number21276462
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