| DOI | Resolve DOI: https://doi.org/10.1016/0040-4039(95)01666-6 |
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| Author | Search for: Vanni, R.1; Search for: Garden, S.J.1; Search for: Banks, J.T.1; Search for: Ingold, K. U.1 |
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| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Subject | alkanol; drug synthesis; hydroxylation; reaction analysis |
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| Abstract | The oxidation of 2-cyclopropylpropane by dimethyldioxirane (DMD) to 2-cyclopropyl-propan-2-ol is not a free-radical chain reaction. It is suggested the free-radical chain observed by Minisci et al.8 when alkane / DMD reactions were carried out in the presence of CCl3Br involves H-atom abstraction from the alkane by Cl3,COO· (in air) and by Me2C(O·)OCCl3, as well as by the Cl3C· radical. © 1995. |
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| Publication date | 1995 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21276497 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | e6de0fc6-1325-4233-9dae-8c040a28d638 |
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| Record created | 2015-10-13 |
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| Record modified | 2020-04-29 |
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