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Reactivity of electrophilic μ-phosphinidene complexes with N-heterocyclic carbenes: formation of the first main group element adducts of ‘abnormal’ carbene ligands

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1039/b604150g
AuthorSearch for: 1; Search for: 1; Search for: 1
Affiliation
  1. National Research Council Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
The reactions of Mn2- and Co2-containing μ-PNiPr2 complexes with NCN carbenes afford the ‘abnormal’ carbene adducts [Mn2(CO)8{μ-P(NiPr2)}(4-cyclo-C3H2-1,3-(NR)2))] and [Co2(CO)4(μ-dppm){μ-P(NiPr2)(4-cyclo-C3H2-1,3-(NR)2)}] (R = tBu, adamantyl), respectively.
Publication date
In
  • Chemical Communications, no. 25 (2006): 2699–2701.
LanguageEnglish
NPARC number12329143
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Record identifierda9e4261-ce21-4d82-a825-16a5e4802213
Record created2009-09-10
Record modified2020-04-22
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