| DOI | Resolve DOI: https://doi.org/10.1016/j.cplett.2016.03.019 |
|---|
| Author | Search for: Barclay, A. J.; Search for: Sheybani-Deloui, S.; Search for: Michaelian, K. H.; Search for: Mckellar, A. R. W.1; Search for: Moazzen-Ahmadi, N. |
|---|
| Affiliation | - National Research Council of Canada. Security and Disruptive Technologies
|
|---|
| Format | Text, Article |
|---|
| Abstract | Infrared spectra of the CO₂─CO dimer are observed in the carbon monoxide CO stretch region (≈2150 cm⁻¹). Combination bands yield the first experimental determinations of intermolecular mode frequencies for the planar T-shaped C-bonded form (‘isomer 1’): 24.34 cm ⁻¹ for the in-plane CO rock and 43.96 cm ⁻¹ for the out-of-plane CO rock. These values are significantly higher than the analogous modes of the O-bonded form (‘isomer 2’), previously determined to be 14.19 and 22.68 cm ⁻¹, respectively. New results are also reported for both isomers of the¹²C¹⁸O₂-substituted form of the dimer. Weak ‘satellite bands’ observed for both isomers are tentatively assigned to the trimer He─CO₂─CO. |
|---|
| Publication date | 2016-03-11 |
|---|
| Publisher | Elsiever |
|---|
| In | |
|---|
| Language | English |
|---|
| Peer reviewed | Yes |
|---|
| Identifier | S0009261416301282 |
|---|
| NPARC number | 23000115 |
|---|
| Export citation | Export as RIS |
|---|
| Report a correction | Report a correction (opens in a new tab) |
|---|
| Record identifier | d9102373-5f86-4324-a8f3-055a1c679189 |
|---|
| Record created | 2016-06-03 |
|---|
| Record modified | 2020-03-16 |
|---|
