Rate of reaction of phenyl radicals with oxygen in solution and in the gas phase

DOI	Resolve DOI: https://doi.org/10.1021/j100134a001
Author	Search for: Sommeling, P.M.; Search for: Mulder, P.; Search for: Louw, R.; Search for: Avila, D.V.¹; Search for: Lusztyk, J.¹; Search for: Ingold, K. U.¹
Name affiliation	National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
Format	Text, Article
Abstract	The rate constant for the title reaction, k1, is 3.8 × 109 M-1 s-1 in water at 298 K and is ≥ 108 M-1 s-1 in the gas phase at 603 K. It is concluded that two reports8,11 that this reaction is very slow in the gas phase, k1 ≤ 1.2 × 104 and ∼2.3 × 106 M-1 s-1, are in error. © Copyright 1993 by the American Chemical Society.
Publication date	1993
In	The Journal of Physical Chemistry 97, no. 32 (1993): 8361–8364.
Language	English
Peer reviewed	Yes
NPARC number	21276772
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Record identifier	d5a3b16d-25f9-41de-9ff3-e8495cce533d
Record created	2015-10-13
Record modified	2020-04-24