Rate of reaction of phenyl radicals with oxygen in solution and in the gas phase

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/j100134a001
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Name affiliation
  1. National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Journal titleThe Journal of Physical Chemistry
ISSN0022-3654
Volume97
Issue32
Pages8361–8364
Abstract
The rate constant for the title reaction, k1, is 3.8 × 109 M-1 s-1 in water at 298 K and is ≥ 108 M-1 s-1 in the gas phase at 603 K. It is concluded that two reports8,11 that this reaction is very slow in the gas phase, k1 ≤ 1.2 × 104 and ∼2.3 × 106 M-1 s-1, are in error. © Copyright 1993 by the American Chemical Society.
Publication date
LanguageEnglish
Peer reviewedYes
NPARC number21276772
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