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Bis[μ-1,2-bis(2-pyridyl)ethyne-κ²N:N']bis[aquadinitratocadmium(II)]

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1107/S0108270103008904
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FormatText, Article
Abstract
Two twisted 1,2-bis(2-pyridyl)ethyne ligands bridge two Cd2+ centers in the C2-symmetric title complex, [Cd2(NO3)4([mu]-C12H8N2)2(H2O)2]. The bridging ligands arch across one another creating a `zigzag loop' molecular geometry. Two nitrate ions and a water molecule complete the irregular seven-coordinate Cd-atom environment. The dihedral angles between the equivalent pyridyl ring planes of the two independent ligands are 67.2 (1)°. Owater-H...Onitrate hydrogen bonding creates two-dimensional layers parallel to the ab plane.
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In
  • Acta Crystallographica Section C 59, no. 6 (2003): m234–m236.
LanguageEnglish
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NPARC number12327327
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Record identifierd0a97e0f-1ea7-4c47-bc47-1a4433bb6f8e
Record created2009-09-10
Record modified2024-03-06
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