| DOI | Resolve DOI: https://doi.org/10.1080/15435070903364764 |
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| Author | Search for: Min, K.1; Search for: Sun, C. W.1; Search for: Qu, W.1; Search for: Zhang, X. G.; Search for: Yick, S.1; Search for: Robertson, M.1; Search for: Decès-Petit, C.; Search for: Hui, R.1 |
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| Affiliation | - National Research Council Canada. NRC Institute for Fuel Cell Innovation
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| Format | Text, Article |
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| Subject | solid oxide fuel cells; cathode; interconnect; chromium poisoning; low temperature |
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| Abstract | Rapid performance degradations of solid oxide fuel cells were observed when the chromium-forming metallic alloys were used as interconnects. The formation of strontium chromium oxide (SrCrO4) on the surface of Sr-doped perovskite cathode was believed to be one of the main causes for the cell degradation. This chromium-poisoning effect was not mitigated when the operating temperature was lowered to 600°C. The SrCrO4 that formed mainly on the cathode surface was found in both La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) and Sm0.5Sr0.5CoO3 (SSCo) cathode, suggesting that all strontium-containing cathodes may develop low conductive chromite oxide compounds. However, this chromium-poisoning effect can be effectively mitigated by coating a protective layer on the surface of the interconnect. |
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| Publication date | 2009-12-09 |
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| Publisher | Taylor & Francis |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 23004797 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | d01abc5b-8d8b-4eb8-baed-35de3109dea8 |
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| Record created | 2018-12-20 |
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| Record modified | 2020-04-16 |
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