DOI | Resolve DOI: https://doi.org/10.1139/p04-073 |
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Author | Search for: Steinitz, Michael O.; Search for: Pink, David A.; Search for: Clancy, J. Patrick; Search for: MacDonald, A. Nicole; Search for: Swainson, Ian1 |
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Affiliation | - National Research Council of Canada. NRC Canadian Neutron Beam Centre
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Format | Text, Article |
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Abstract | Capacitance dilatometry was used to measure the relative thermal expansivity, ΔL/L₀, of single crystals of sodium nitrate (NaNO₃) as a function of temperature. From these measurements, the phase transition at Tf = 550 K shows characteristics of a discontinuous transition. A theory based on the competition between long-range interactions and the entropy gained by rotating NO3⁻₃ groups at high temperatures predicts a discontinuous transition at T = Tf with ΔL/L₀ sim (Tf – T)ζ with ζ = 1. Our measurements yield ζ ≈ 1. |
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Publication date | 2004-11-30 |
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Publisher | National Research Council of Canada. NRC Research Press |
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In | |
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NPARC number | 12328115 |
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Export citation | Export as RIS |
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Report a correction | Report a correction (opens in a new tab) |
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Record identifier | ca832c56-5b69-462d-8cfd-0a2ffffb8d60 |
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Record created | 2009-09-10 |
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Record modified | 2022-10-13 |
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