Solvent induced frequency shifts of the C—H stretching bands of n-octane. A Fourier transform infrared study

DOI	Resolve DOI: https://doi.org/10.1139/v81-199
Author	Search for: Cameron, D. G.¹; Search for: Hsi, S. C.¹; Search for: Umemura, J.¹; Search for: Mantsch, H. H.¹
Name affiliation	National Research Council of Canada
Format	Text, Article
Journal title	Canadian Journal of Chemistry
ISSN	0008-4042 1480-3291
Volume	59
Issue	9
Pages	1357–1360
Abstract	Using a Fourier transform spectrometer the frequencies and bandwidths of the infrared active C—H stretching modes of n-octane were determined in a variety of solvents with refractive indices from 1.63 (carbon disulfide) to 1.28 (n-perfluorooctane), and dielectric constants from 37.5 (acetonitrile) to 1.8 (n-perfluorooctane). The frequency shifts were correlated with the refractive indices and dielectric constants of the solvents, and fitted with the equation of David and Hallam (Spectrochim. Acta, Part A, 23, 593 (1967)). Generally, solution results in shifts to frequencies lower than those observed in the gas phase. However, solution in n-perfluorooctane resulted in a shift to a higher frequency, behavior in accord with the above equation but not previously observed.
Publication date	1981-05
Language	English
Peer reviewed	Yes
NRC number	NRCC 19040
NPARC number	23001400
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Record identifier	ca3fbb0c-e601-4308-befa-96c6aa53f153
Record created	2017-02-02
Record modified	2020-03-13