| DOI | Resolve DOI: https://doi.org/10.1021/ja050155c |
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| Author | Search for: Martin-Redondo, M.; Search for: Scoles, Ludmila1; Search for: Sterenberg, B.; Search for: Udachin, K.; Search for: Carty, A. |
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| Affiliation | - National Research Council of Canada. NRC Institute for Chemical Process and Environmental Technology
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| Format | Text, Article |
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| Abstract | Reaction of [Pt(CH3)2(COD)] (COD = 1,5-cyclooctadiene) with Ph2PCCCCPPh2 led to a mixture of [{Pt(CH3)2}2(-Ph2PC4PPh2)2] (1) and [{Pt(CH3)2}3(-Ph2PC4PPh2)3] (2). Reaction of [PtCl2(COD)] with Ph2PCCCCPPh2 led to a mixture of the thermally unstable compounds [{PtCl2}2(-Ph2PC4PPh2)2] (3) and [{PtCl2}3(-Ph2PC4PPh2)3] (4) which transform into [{PtMe2}2{-C8(PPh2)4}] (5) and [{PtMe2}3{3-C12(PPh2)6}] (6) containing 8-membered diene-diyne and 12-membered triene-triyne rings, respectively. Compound 2 can be converted to [{PtMe2}3{C12(PPh2)6}] (7) by heating with CuCl at 80 C, while 1 can be heated without significant cycloaddition. |
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| Publication date | 2005-04-13 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 12327962 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | c9d4b160-1308-42ea-b631-974f663f89cc |
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| Record created | 2009-09-10 |
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| Record modified | 2020-04-07 |
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