| DOI | Resolve DOI: https://doi.org/10.1139/v66-006 |
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| Author | Search for: Young, Robert1; Search for: Adams, G.A.1 |
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| Affiliation | - National Research Council of Canada
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| Format | Text, Article |
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| Abstract | Condensation of D-talose with nitromethane in alkaline methanol gave the corresponding epimeric 1-deoxy-1-nitroheptitols which were converted into D-glycero-L-altro-heptose and D-glycero-L-allo-heptose (1.5:1) in 44% yield. Reduction of D-glycero-L-altro-heptose with sodium borohydride gave the hitherto unknown meso-glycero-altro-heptitol. The gas–liquid chromatography retention times of the 10 geometrically isomeric heptitol heptaacetates were determined. These data provide the necessary information for the key step in a procedure for the rapid identification of an unknown heptose. |
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| Publication date | 1966 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NRC number | NRCC 8730 |
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| NPARC number | 21274526 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | c62a2d4a-7843-476c-8022-ea3f827981e4 |
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| Record created | 2015-03-16 |
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| Record modified | 2020-03-12 |
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