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Vibrational-rotational structure in the resonance Raman effect of iodine vapor

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1016/0022-2852(72)90048-3
AuthorSearch for: 1; Search for: 1
Affiliation
  1. National Research Council of Canada
FormatText, Article
Abstract
The overtone progression in the resonance Raman effect of iodine vapor shows a remarkably fine structure. The observed resonance Raman lines can be explained in terms of Q branches, S bandheads and vibrational “hot” band structure. Comparing the observed Raman spectra with calculated Q, S and O branches, using spectroscopic constants derived from the high resolution fluorescence measurements of Rank and Rao, we have been able to assign all observed Raman lines. The spectroscopic constants ωe and ωexe for the ground state of iodine have been determined, whereas the constants ωeye and αe could only be estimated.
Publication date
PublisherElsevier
In
  • Journal of Molecular Spectroscopy 43, no. 3: 366–381.
NoteThe authors were affiliated with the National Research Council of Canada, Division of Chemistry when they authored this article.
LanguageEnglish
Peer reviewedYes
NRC numberNRCC 12699
NPARC number23002986
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Record identifierc2c95d0e-7c49-4380-a305-71e598731ac2
Record created2018-04-04
Record modified2020-03-13
Date modified: