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Surface photochemistry: ¹³C enrichment by photolysis on silica gel

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DOIResolve DOI: https://doi.org/10.1139/v84-341
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Abstract
The enrichment of the ¹³C isotope by partial photolysis of dibenzyl ketone on silica gel has been demonstrated. The ¹³C enrichment is substantial and is parallel to the increase in the probability of geminate radical recombination on a silica surface as compared with that in solution. A substantial ¹³C enrichment was also observed for the rearranged starting material, 1-phenyl-4′-methylacetophenone. The single-stage isotope separation factors are different for the two ketones although both are isomers derived from the same benzyl–phenylacetyl radical pairs.
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  • Canadian Journal of Chemistry 62, no. 10 (1984): 1999–2005.
LanguageEnglish
Peer reviewedYes
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NPARC number12329049
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Record identifierbc5e36b3-ec47-4296-87d3-5bae9ebc2c34
Record created2009-09-10
Record modified2023-05-04
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