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Kinetic applications of electron paramagnetic resonance spectroscopy. XII. Self-reactions of some phosphorus centered radicals

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/ja00809a036
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Affiliation
  1. National Research Council of Canada
FormatText, Article
Abstract
The rates of the bimolecular self-reactions of a variety of phosphorus centered radicals have been studied by kinetic epr spectroscopy. In the absence of steric effects, planar phosphinyl radicals, e.g., (EtO)2P, tetrahedral phosphonyl radicals, e.g., (EtO)2Ṗ=O, and trigonal bipyramidal phosphoranyl, e.g., t-BuOṖ(OEt)2Cl, and spirophosphoranyl, e.g., OCH2CH2OṖOCH2CH2O, radicals react at (or close to) the diffusion-controlled limit.
Publication date
In
  • Journal of the American Chemical Society 96, no. 2 (1974): 554–556.
LanguageEnglish
Peer reviewedYes
NPARC number21276742
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Record modified2020-03-13
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