| DOI | Resolve DOI: https://doi.org/10.1016/0022-0728(96)04601-3 |
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| Author | Search for: Andersen, Mogens L.1; Search for: Wayner, Danial D. M.1 |
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| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Abstract | The kinetics of the fast unimolecular fragmentation of α-aryloxyacetophenone radical anions in DMF has been analyzed by using a combination of linear sweep voltammetry and independently determined standard potentials or rate constants. The cleavage rates are in the range 3.8 × 10⁵ s⁻¹ to 2.8 × 10⁸ s⁻¹. The mechanism changes from a predominantly DISP mechanism to a predominantly ECE mechanism at fast cleavage rates. It was found that the effect of the heterogeneous electron transfer cannot be neglected when reactions with rate constants above 105 s⁻¹ are studied by linear sweep voltammetry. |
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| Publication date | 1996-08-29 |
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| In | |
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| Language | English |
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| NPARC number | 12327640 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 9c63e016-629d-471f-ad34-d37cfe64170d |
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| Record created | 2009-09-10 |
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| Record modified | 2020-03-20 |
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