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Describing chemical transformations in multiple spiking isotope dilution: fundamental aspects and definitions

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1039/B814388A
AuthorSearch for: 1ORCID identifier: https://orcid.org/0000-0002-3349-5535; Search for: 1; Search for: 1ORCID identifier: https://orcid.org/0000-0002-2377-2615
Affiliation
  1. National Research Council of Canada. NRC Institute for National Measurement Standards
FormatText, Article
Abstract
Currently, several mathematical methods exist to address simultaneous species formation and degradation using multiple spiking isotope dilution mass spectrometry. While all of these strategies have been compared numerically, comparison of the underlying principles is lacking. Owing to recent interest in using the species inter-conversion factors, mainly to study the quality of analytical methods, this manuscript reviews the mathematical logic and inconsistencies of the existing double or triple spiking isotope dilution models. Systematic terminology is also introduced to clarify the species inter-conversion coefficient definitions.
Publication date
PublisherRoyal Society of Chemistry
In
  • The Analyst 134, no. 3: 466–471.
LanguageEnglish
Peer reviewedYes
NPARC number23001626
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Record identifier9952c5bc-d035-49e0-9b7a-fa4ed908c434
Record created2017-03-13
Record modified2020-04-16
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