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Reassignment of the low lying cationic states in gas phase adenine and 9-methyl adenine

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1016/j.cplett.2006.08.122
AuthorSearch for: 1; Search for: 1; Search for: 1
Affiliation
  1. National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
Using time-resolved photoelectron spectroscopy results, we reassign the electronic character and ionization energies of the low lying cationic states of adenine and 9-methyl adenine. For adenine, the state ordering is D0(π−1) = 8.5 eV, D1(n−1) = 9.6 eV, D2(π−1) ≈ D3(n−1) ≈ 10.5 eV. For 9-methyl adenine, the assignment is the same with values of D0(π−1) = 8.4 eV, D1(n−1) = 9.4 eV, D2(π−1) ≈ D3(n−1) ≈ 10.2 eV
Publication date
In
  • Chemical Physics Letters 430, no. 1-3 (19 October 2006): 144–148.
LanguageEnglish
Peer reviewedYes
NPARC number12327292
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Record identifier8863a7b7-2aad-4783-aaf3-48d4370d7bdc
Record created2009-09-10
Record modified2023-06-23
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