Language selection

Government of Canada / Gouvernement du Canada

Search

The oxidation of (+)-occidentalol with t-butyl chromate

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1039/p19720000962
AuthorSearch for: ; Search for: ; Search for: 1
Affiliation
  1. National Research Council of Canada. Prairie Regional Laboratory
FormatText, Article
Abstract
The oxidation of (+)-occidentalol (1) with t-butyl chromate affords 8-(1-hydroxy-1-methylethyl)-1,5-dimethyl-bicyclo[4,4,0]dec-4-ene-2,3-dione (3), (+)-2-hydroxy-9-(1-hydroxy-1-methylethyl)-2,6-dimethylbicyclo [4,4,0]-dec-4-en-3-one (4), (+)-3-[2-carboxy-5-(1-hydroxy-1-methylethyl)-2-methylcyclohexyl]but-2-enoic acid (6), and (+)-3-(1-hydroxy-1-methylethyl)-6,9-dimethyl-8-oxabicyclo[4,3,0]non-9-en-7-one (8). Mechanistic implications of the oxidation, based on the various products identified, are discussed.
Publication date
PublisherRoyal Society of Chemistry
In
  • Journal of the Chemical Society, Perkin Transactions 1 (1972): 962–.
LanguageEnglish
Peer reviewedYes
IdentifierNRCC-12950
Export citationExport as RIS
Report a correctionReport a correction (opens in a new tab)
Record identifier84eecb9f-71b4-4ac4-ab9c-a2dec8255623
Record created2023-11-07
Record modified2023-11-07
Date modified: