| Download | - View accepted manuscript: Polymeric and polymer-ligated spirobicyclic zwitterionic Janovsky complexes (PDF, 641 KiB)
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| DOI | Resolve DOI: https://doi.org/10.1016/j.tetlet.2009.03.136 |
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| Author | Search for: Culf, Adrian S.; Search for: Werner-Zwanziger, Ulrike; Search for: Robertson, Katherine N.; Search for: Chen, Banghao; Search for: Cuperlovic-Culf, Miroslava1; Search for: Barnett, David A.; Search for: Ouellette, Rodney J. |
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| Affiliation | - National Research Council of Canada. NRC Institute for Information Technology
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| Format | Text, Article |
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| Subject | Janovsky; spirobicyclic; solid-phase synthesis; NMR; anionic sigma complex |
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| Abstract | A novel approach to the synthesis of spirobicyclic Janovsky complexes is described. The complexes were prepared on silica and polystyrene polymeric supports as well as on a solution-borne poly(carbodiimide) polymer with 100% atom economy. A carbon-centered intramolecular de-aromatizing nucleophilic aromatic substitution ipso-cyclization mechanism describes the synthesis of these spirobicyclics. The molecules were characterized by solution and solid-state ¹H and ¹³C NMR, IR, and MS. |
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| Publication date | 2009-03-25 |
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| Publisher | Elsevier |
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| Place | Amsterdam, Netherlands |
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| Access condition | |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NRC number | NRCC 50797 |
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| NPARC number | 15336789 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 7aafa89d-541f-4089-8ba5-c226a77ccac4 |
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| Record created | 2010-06-10 |
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| Record modified | 2020-12-17 |
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