| DOI | Resolve DOI: https://doi.org/10.1021/j150659a002 |
|---|
| Author | Search for: Doba, T.1; Search for: Ingold, K. U.1; Search for: Siebrand, W.1; Search for: Wildman, T.A.1 |
|---|
| Affiliation | - National Research Council of Canada
|
|---|
| Format | Text, Article |
|---|
| Abstract | Rate constants are reported for hydrogen and deuterium abstraction by methyl radicals in CH3OH and CD3OD glasses in the ranges 5-89 and 77-97 K, respectively. At each temperature, they show a distribution due to a variation of radical trapping sites. The rate constants of this distribution are analyzed theoretically to yield a quantitative relation between tunneling rate and equilibrium tunneling distance. |
|---|
| Publication date | 1984 |
|---|
| In | |
|---|
| Language | English |
|---|
| Peer reviewed | Yes |
|---|
| NPARC number | 21276639 |
|---|
| Export citation | Export as RIS |
|---|
| Report a correction | Report a correction (opens in a new tab) |
|---|
| Record identifier | 731dbf9d-ab93-48e7-9cb3-36e586d58829 |
|---|
| Record created | 2015-10-13 |
|---|
| Record modified | 2020-03-13 |
|---|
