| DOI | Resolve DOI: https://doi.org/10.1016/j.jms.2015.02.006 |
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| Author | Search for: McKellar, A. R. W.1; Search for: Billinghurst, B. E. |
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| Affiliation | - National Research Council Canada. Security and Disruptive Technologies
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| Format | Text, Article |
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| Subject | Aldehydes; Infrared radiation; Infrared spectroscopy; Light sources; Synchrotron radiation; Synchrotrons; Acrolein; Coriolis; Excited vibrational state; Experimental characterization; Perturbation; Rotational analysis; Synchrotron radiation facility; Vibrational levels; Herbicides |
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| Abstract | The weak combination bands ν12 +ν18 and ν17 +ν18 of trans-acrolein in the 700-760cm-1 region are observed at high resolution (<0.001cm-1) using spectra obtained at the Canadian Light Source synchrotron radiation facility. A detailed rotational analysis of the 121181 and 171181 upper states is made which includes the nearby perturbing states 185, 132181, and 131183. Taking the results of this 5-state fit, together with earlier results on lower lying vibrations, we now have experimental characterization for all 15 excited vibrational states of acrolein lying below 820cm-1. |
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| Publication date | 2015-02-23 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21275821 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 6ba47805-7a3d-4fdb-8126-1fa5358b624e |
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| Record created | 2015-07-14 |
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| Record modified | 2020-04-22 |
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