Language selection

Government of Canada / Gouvernement du Canada

Search

A Putative Monooxygenase Mimic Which Functions via Well-Disguised Free Radical Chemistry

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/ja963627j
AuthorSearch for: ; Search for: 1; Search for: 1; Search for:
Affiliation
  1. National Research Council Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
The hydroxylation of cycloalkanes at 25 C by the syringe pump addition of tert-alkyl hydroperoxides (10 and 1 equiv based on catalyst) to deoxygenated acetonitrile containing cycloalkanes (0.64 M) and 0.61 mM of the catalyst, [FeIII2O(TPA)2(H2O)2]4+, is demonstrated to be a reaction which involves freely diffusing cycloalkyl radicals, i.e., free alkyl radicals.
Publication date
In
  • JACS: Journal of the American Chemical Society 119, no. 44: 10594–10598.
LanguageEnglish
Peer reviewedYes
NPARC number12337874
Export citationExport as RIS
Report a correctionReport a correction (opens in a new tab)
Record identifier5cf34322-5e32-4acc-a23b-1d901db3d29e
Record created2009-09-10
Record modified2020-03-20
Date modified: