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The alpha and beta 1,3,4,6-tetraacetyl-D-glucopyranoses and their chloroacetyl derivatives

From National Research Council Canada

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DOIResolve DOI: https://doi.org/10.1139/v53-136
AuthorSearch for: 1; Search for: 1
Affiliation
  1. National Research Council of Canada. Prairie Regional Laboratory
FormatText, Article
Abstract
Reaction of 3,4,6-triacetyl-β-D-glucopyranosyl chloride with silver acetate in acetic acid gave 1,3,4,6-tetraacetyl-α-D-glucopyranose, m.p. 97–98 °C., [α]D + 145° (chloroform). 3,4,6,-Triacetyl-α-D-glucopyrartosyl chloride, m.p. 93–94 °C., [α]D + 185° (chloroform), prepared from the β-anomer by isomerization in acetone, with silver acetate in acetic acid gave 1,3,4,6-tetraacetyl-β-D-glucopyranose, m.p. 137–138 °C., [α]D + 26° (chloroform). The structures of these glucose tetraacetates were established by the interconversion of chloroacetyl derivatives.
Publication date
PublisherCanadian Science Publishing
In
  • Canadian Journal of Chemistry 31, no. 11 (1 November 1953): 1040–1047.
LanguageEnglish
Peer reviewedYes
IdentifierNRCC-3077
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Record identifier59590406-2b4d-4466-a41d-48ffc30ff5fe
Record created2023-09-14
Record modified2023-09-14
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