| DOI | Resolve DOI: https://doi.org/10.1063/1.1331636 |
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| Author | Search for: Blanchet, V.1; Search for: Zgierski, M. Z.2; Search for: Stolow, Albert2 |
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| Affiliation | - National Research Council of Canada
- National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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| Format | Text, Article |
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| Subject | nonradiative transitions; photoelectron spectra; polymers; time resolved spectra |
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| Abstract | We examine the role of electronic continua in time-resolved photoelectron spectroscopy studies of polyatomic nonadiabatic dynamics. We have investigated the two limiting cases for such studies. We consider here the limiting case of complementary ionization correlations where the two nonadiabatically coupled excited electronic states (Sā and Sā) correlate (in the Koopmans' picture) to different cation electronic states. We show, using an example of ultrafast internal conversion a linear polyene, that this favorable case allows for disentangling of the electronic population dynamics from the coupled vibrational dynamics. In the following paper, we investigate the unfavorable case of corresponding ionization correlations. |
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| Publication date | 2001-01-15 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 12328056 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 58dc33ad-42d6-4e82-b1a1-466a2071f2c5 |
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| Record created | 2009-09-10 |
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| Record modified | 2020-03-27 |
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