| DOI | Resolve DOI: https://doi.org/10.1039/D3TC00486D |
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| Author | Search for: Lu, Yao-Chih; Search for: Anedda, Roberto1; Search for: Chen, Hsiu-HuiORCID identifier: https://orcid.org/0000-0002-5916-7150; Search for: Hsu, Hui-Chu; Search for: Hsu, Shun-Ju; Search for: Ratcliffe, Christopher2; Search for: Lai, Long-LiORCID identifier: https://orcid.org/0000-0002-2152-0430; Search for: Ripmeester, John2; Search for: Hsu, Hsiu-Fu |
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| Affiliation | - National Research Council of Canada
- National Research Council of Canada. Security and Disruptive Technologies
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| Funder | Search for: Ministry of Science and Technology, Taiwan |
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| Format | Text, Article |
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| Abstract | A dendrimer with three-fold symmetry and piperazinoamido moieties was prepared in ∼35% yield. This molecule was observed to exhibit columnar phases on thermal treatment and have free void space in the mesogenic and solid states based on a ¹²⁹Xe-NMR study. The piperazinoamido moiety was indicated in a theoretical calculation to cause the dendritic framework to become twisted between the central core and periphery—thus resulting in the dendrimer forming a free void space inside the framework after having self-assembled into columnar stacks. |
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| Publication date | 2023-02-28 |
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| Publisher | Royal Society of Chemistry |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 55a6a16e-5eef-4e6e-9809-9f68c4e04769 |
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| Record created | 2023-09-12 |
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| Record modified | 2023-09-12 |
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