Fourier self-deconvolution : a method for resolving intrinsically overlapped bands

DOI	Resolve DOI: https://doi.org/10.1366/0003702814732634
Author	Search for: Kauppinen, Jyrki K.¹; Search for: Moffatt, Douglas J.¹; Search for: Mantsch, Henry H.¹; Search for: Cameron, David G.¹
Name affiliation	National Research Council Canada
Format	Text
Type	Article
Journal title	Applied Spectroscopy
ISSN	0003-7028 1943-3530
Volume	35
Issue	3
Pages	271–276
Subject	Fourier transform; Infrared; Deconvolution; Computer, applications
Abstract	The general theory of Fourier self-deconvolution, i.e., spectral deconvolution using Fourier transforms and the intrinsic lineshape, is developed. The method provides a way of computationally resolving overlapped lines that can not be instrumentally resolved due to their intrinsic linewidth. Examples of the application of the technique to synthetic and experimental infrared spectra are presented, and potential applications are discussed. It is shown that lines in spectra having moderate signal/noise ratios (∼1000) can readily be reduced in width by a factor of 3. The method is applicable to a variety of spectroscopic techniques.
Publication date	1981-05-01
Publisher	Society for Applied Spectroscopy
Language	English
Peer reviewed	Yes
NPARC number	23001296
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Record identifier	5440c549-527d-4076-89ea-5ad209af89fd
Record created	2017-01-13
Record modified	2020-03-13