| Abstract | A method for determination of aluminium phosphide (AlP) in fumigants by inductively coupled plasma optical emission spectrometry (ICP OES) is presented. An 8 hour hydrolysis in water achieved complete decomposition of AlP with the released PH3 being absorbed in a medium of KMnO4/H2SO4. The solution was treated with NH2OH.HCl to reduce the excess MnO4- and the PO4-3 so formed was quantitated as P by ICP OES based on external calibration using the P(I) 213.618 nm emission line. A detection limit (3s, n=10) of 0.26 g/100 g AlP and LOQ (10s, n=10) of 0.85 g/100g AlP were realized. Ten commercial samples of fumigants were analysed, providing results in agreement with specifications of ~ 55-60 g/100g and concordant with values generated by the spectrophotometric method, as evidenced by a paired t-test (95% confidence limit).This simple procedure has been adopted by the Institute of Technology of Paraná - TECPAR (Curitiba, Brazil). |
|---|
