Chemically induced dynamic electron polarization of dialkoxyphosphonyl radicals

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/j100233a007
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  1. National Research Council Canada
FormatText
TypeArticle
Journal titleThe Journal of Physical Chemistry
ISSN0022-3654
Volume87
Issue10
Pages1674–1675
Abstract
The EPR spectra of phosphonyl radicals, (RO) 2Ṗ=O, which are characterized by a well-spaced (∼700 G) doublet, show an impressive E-A polarization when generated by photolysis of a 20% (v/v) solution of a dialkyl phosphite in di-tert-butyl peroxide.
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LanguageEnglish
Peer reviewedYes
NPARC number21276479
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Record identifier47c03600-40b1-45c1-aafc-e192d57f0c9a
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Record modified2020-03-13
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