| Download | - View final version: Emergent rhombus tilings from molecular interactions with M-fold rotational symmetry (PDF, 1 MB)
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| DOI | Resolve DOI: https://doi.org/10.1103/PhysRevLett.114.115702 |
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| Author | Search for: Whitelam, Stephen; Search for: Tamblyn, Isaac; Search for: Garrahan, Juan P.; Search for: Beton, Peter H. |
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| Format | Text, Article |
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| Abstract | We show that model molecules with particular rotational symmetries can self-assemble into network structures equivalent to rhombus tilings. This assembly happens in an emergent way, in the sense that molecules spontaneously select irregular fourfold local coordination from a larger set of possible local binding geometries. The existence of such networks can be rationalized by simple geometrical arguments, but the same arguments do not guarantee a network’s spontaneous self-assembly. This class of structures must in certain regimes of parameter space be able to reconfigure into networks equivalent to triangular tilings. |
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| Publication date | 2015-03-20 |
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| Publisher | American Physical Society |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 23003153 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 38f1c16d-7091-4ca1-818d-cc0b49b831b4 |
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| Record created | 2018-05-02 |
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| Record modified | 2020-05-30 |
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