High performance liquid chromatographic-mass spectrometric detection of giant fullerenes

DOI	Resolve DOI: https://doi.org/10.1002/jhrc.1240160204
Author	Search for: Anacleto, Joseph F.; Search for: Boyd, Robert K.; Search for: Quilliam, Michael A.¹
Name affiliation	National Research Council of Canada. NRC Institute for Marine Biosciences
Format	Text, Article
Journal title	Journal of High Resolution Chromatography
ISSN	0935-6304 1521-4168
Volume	16
Issue	2
Pages	85–89
Abstract	Fullerene-rich soot generated by resistive heating of graphite has been gently extracted with toluene, in order to remove some C60 and C70 compounds, followed by extraction with boiling 1,2,4-trichlorobenzene at 214°C. After filtration and removal of the solvent, the residue was re-dissolved in dichloromethane and characterized by non-aqueous reversed phase liquid chromatography coupled on-line with atmospheric pressure chemical ionization mass spectrometry. Several novel fullerenes were detected, including C72, C80, C86, and C88 as well as other fullerenes up to C108 and higher. The results indicate that chromatographic separation of large fullerene molecules can be achieved with low boiling point solvents and conventional liquid chromatographic techniques.
Publication date	1993-02
Language	English
Peer reviewed	Yes
NPARC number	23001022
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Record identifier	33376cea-0ff8-4e5f-b26e-ca55b7de7a32
Record created	2016-11-29
Record modified	2020-04-24