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Variable-temperature and -pressure vibrational spectra of o-carborane

DOIResolve DOI: https://doi.org/10.1021/ic00309a013
AuthorSearch for: 1ORCID identifier: https://orcid.org/0000-0001-5195-1138; Search for: ; Search for: ; Search for: ; Search for:
Affiliation
  1. National Research Council Canada. NRC Institute for Research in Construction
FormatText, Article
Abstract
Variable-temperature Raman and FT-IR spectra of solid o-carborane have been measured. Three phases (one of which is time-dependent) were detected by Raman spectroscopy, whereas four were found by using the IR technique. Variable-pressure Raman spectra up to 70 kbar revealed a phase transition at 10.1 kbar, with pressure coefficients of 1.3 and 0.75 cm⁻¹/kbar for the in-phase, B-B stretching mode of the icosahedral cage at 773 cm⁻¹ in the low- and high-pressure phases, respectively.
Date published
PublisherAmerican Chemical Society
In
  • Inorganic Chemistry 28, no. 10 (1989): 1819–1823.
LanguageEnglish
Peer reviewedYes
NRC numberNRC-IRC-3120
NPARC number20330255
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Record identifier2f5c19bf-d666-49e1-8925-a88808dddfe8
Record created2012-07-18
Record modified2024-10-03

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