| Abstract | A property which limits the breadth of application of thermoset polymers and their composites is their relatively low maximum operating temperatures. This work investigates the potential application of both functionalized single-walled carbon nanotubes (f-SWCNTs) based on negative charging, and unfunctionalized SWCNTs (u-SWCNTs) to increase the mechanical and thermal performance of a high-temperature aerospace-grade epoxy with a glass transition temperature of approximately 270 C. Thermal and mechanical properties of the baseline epoxy and nanocomposites containing a low content of SWCNTs (0.2 % by weight) were characterized through thermogravimetric analyses, tensile tests, and dynamic mechanical analyses. Tensile tests were performed both at room temperature and at 80 C. Further, room temperature tensile tests were performed on untreated and heat-treated specimens. The heat treatment was performed at 300 C, slightly above the resin glass transition temperature. Results demonstrate that f-SWCNTs are effective in improving the mechanical and thermal performance of the epoxy. No significant improvement was observed for u-SWCNT nanocomposites. For the nanocomposite with f-SWCNTs, the ultimate tensile strength and strain to failure at room temperature (80 C) increased by 20 % (8 %) and 71 % (77 %), respectively, as compared to the baseline epoxy. The f-SWCNT nanocomposite, unlike other examined materials, exhibited a stress-strain necking behavior at 80 C, an indication of increased ductility. After heat treatment, these properties further improved relative to the neat epoxy (160 % increase in ultimate tensile strength and 270 % increase in strain to failure). This work suggests the potential to utilize f-SWCNTs based on negative charging to enhance high-temperature thermoset performance. © 2013 Her Majesty the Queen in Right of Canada. |
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