Electron spin resonance spectrum of oxygen-17 enriched t-alkylperoxy radicals

DOI	Resolve DOI: https://doi.org/10.1021/ja00707a031
Author	Search for: Adamic, K.¹; Search for: Ingold, K. U.¹; Search for: Morton, J.R.¹
Name affiliation	National Research Council of Canada
Format	Text, Article
Abstract	Esr spectra of ROO radicals (R = t-butyl, cumyl) containing oxygen enriched in the isotope 17O, have been detected at -100°. The 17O hyperfine constants were 21.8 ± 0.1 G and 16.4 ± 0.1 G. From the variation in the line widths across the 17O manifolds it was possible to assign these two hyperfine constants to the terminal and inner oxygen nuclei, respectively, and to conclude that the spin density on the terminal oxygen was approximately twice that on the inner.
Publication date	1970
In	Journal of the American Chemical Society 92, no. 4 (1970): 922–923.
Language	English
Peer reviewed	Yes
NPARC number	21276737
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Record identifier	23a3ac08-8c82-4ea2-99d2-29bfb354cf7b
Record created	2015-10-13
Record modified	2020-03-13