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Equal reaction rates for all recombination pathways

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1063/1.473294
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Affiliation
  1. National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Subjectassociation; chemical reactions; potential energy surfaces; reaction rate constants
Abstract
Formal collision theory indicates that the absolute termolecular recombination reaction rate can be expressed in a form associated either with direct or indirect mechanisms for the recombination. Moreover, the same exact rate constant can be calculated using either of the four mechanisms. These results are to be contrasted to the rate constants standardly calculated by approximate methods.
Publication date
In
  • The Journal of Chemical Physics 106, no. 4 (22 January 1997): 1463–1466.
LanguageEnglish
Peer reviewedYes
NRC publication
This is a non-NRC publication

"Non-NRC publications" are publications authored by NRC employees prior to their employment by NRC.

NPARC number12338474
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Record identifier0db94da6-26e7-49f3-86f1-737c4f728051
Record created2009-09-10
Record modified2020-03-20
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