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Revised assignment of the electron spin resonance spectrum obtained during photolysis of N-(diphenylmethylene)methylthiomethylamine N-oxide. The bis(methylthiomethyl) nitroxide radical

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1039/P29760001659
AuthorSearch for: 1; Search for: 1
Name affiliation
  1. National Research Council of Canada
FormatText, Article
Abstract
Photolysis of N-(diphenylmethylene)methylthiomethylamine N-oxide, Ph 2C=N(→-O)CH2SCH3, yields bis(methylthiomethyl) nitroxide, (CH3SCH2)2NO, rather than, as previously reported, the diphenylmethylene(methylene)-amine N-oxyl radical, [Ph2C⋯N(⋯O)⋯CH2]. The e.s.r. spectrum of (CH3SCH2)2NO shows an alternating line width effect at ambient and lower temperatures.
Publication date
In
  • Journal of the Chemical Society, Perkin Transactions 2 14 (1976): 1659–1663.
LanguageEnglish
Peer reviewedYes
NPARC number21276468
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