Revised assignment of the electron spin resonance spectrum obtained during photolysis of N-(diphenylmethylene)methylthiomethylamine N-oxide. The bis(methylthiomethyl) nitroxide radical

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1039/P29760001659
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  1. National Research Council of Canada
FormatText, Article
Journal titleJournal of the Chemical Society, Perkin Transactions 2
ISSN1472-779X
Volume14
Pages1659–1663
Abstract
Photolysis of N-(diphenylmethylene)methylthiomethylamine N-oxide, Ph 2C=N(→-O)CH2SCH3, yields bis(methylthiomethyl) nitroxide, (CH3SCH2)2NO, rather than, as previously reported, the diphenylmethylene(methylene)-amine N-oxyl radical, [Ph2C⋯N(⋯O)⋯CH2]. The e.s.r. spectrum of (CH3SCH2)2NO shows an alternating line width effect at ambient and lower temperatures.
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LanguageEnglish
Peer reviewedYes
NPARC number21276468
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