| DOI | Resolve DOI: http://doi.org/10.1107/S0365110X60001308 |
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| Author | Search for: Kartha, G.1 ; Search for: Ahmed, F.R.1 ; Search for: Barnes, W.H.1 |
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| Name affiliation | - National Research Council Canada
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| Type | Article |
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| Journal title | Acta Crystallographica |
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| ISSN | 0365-110X |
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| Volume | 13 |
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| Issue | 7 |
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| Pages | 525–531; # of pages: 7 |
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| Abstract | The structure of the hydrochloride DL-alphaprodine has been determined by the isomorphous replacement method with the aid of data for the hydrobromide. Zero-level normal, and first-level generalized, projections along the three axes have been employed. The structure has been refined by three-dimensional Fourier and differential syntheses. The stereochemical configuration found for the alphaprodine molecule agrees with that of one of four possible isomers and confirms that proposed by Beckett and co-workers on conformational and other grounds. The piperidine ring has the chair form with the phenyl ring equatorial and the propionoxy chain axial; the methyl group on C(3) is trans to the phenyl ring on C(4). |
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| Publication date | 1960 |
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| Note | Addendum to this paper available in Acta Crystallographica, Volume 14 (1), January 1961. (NRCC 6054). |
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| Language | English |
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| Peer reviewed | Yes |
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| NRC number | 5621 |
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| NPARC number | 21274957 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction |
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Record identifier | 06d0e467-7a5a-43c2-8b73-9adc5c347317 | | Record created | 2015-05-04 |
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| Record modified | 2016-05-09 |
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