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Free radicals by mass spectrometry. VI. The bond dissociation energies of some methyl, allyl, and benzyl compounds by electron impact

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1063/1.1740445
AuthorSearch for: 1; Search for: 1; Search for: 1
Affiliation
  1. National Research Council of Canada
FormatText, Article
Abstract
The appearance potentials for the radical ions from methyl, allyl, and benzyl halides and two other derivatives have been measured. Using previously measured values for the ionization potentials of the free radicals, the R - X bond dissociation energies in these compounds have been calculated. The results are in good agreement with published data for the methyl and allyl compounds, and in fair agreement for the benzyl halides.
Publication date
In
  • The Journal of Chemical Physics 22, no. 9 (1954): 1489–1492.
LanguageEnglish
Peer reviewedYes
NPARC number21276625
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Record identifier03309da1-ab66-4935-9375-4a5c5ff81eb0
Record created2015-10-13
Record modified2020-03-12
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